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Generally, IPMCs
in alkali metal cations will show electrolysis when applying a high DC
voltage, which is another barrier to obtain a large displacement. This
undesired electrochemical reaction consumes power and may damage the
electrode by producing gas. However, this phenomenon is not obvious in TBA
form. Especially for Flemion-based IPMC, which can suppress electrolysis up
to 3 volts. Remarkable displacement was observed is such kind of sample, as
is shown in Figure, 3 volts of DC potential was applied across a
Flemion-based IPMC with the counter ion of TBA. The sample bent continuously
toward anode (with decreasing speed). After 3 and half minutes, its
configuration nearly reached a circle.
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